THE REACTION OF CF3OOCF2OF WITH FLUOROOLEFINS

Author(s): RUSSO, A; MONTANARI, V; NAVARRINI, W; DESMARTEAU, DD.

Source: JOURNAL OF FLUORINE CHEMISTRY

Volume: 74 Issue: 1 Pages: 83-87

DOI: 10.1016/0022-1139(95)03243-7 Published: SEP 1995.

ABSTRACT

The reaction of fluoroxydifluoromethyl trifluoromethyl peroxide, CF3OOCF2OF (1), with fluoroolefins leads to the formation of novel fluorinated peroxides as major products. When 1 was added to 1,2-dichloro-1,2-difluoroethylene, CFCl=CFCl, under controlled conditions,the formation of 4,5-dichloro-2,2,4,5-tetrafluoro-1,3-dioxolane was also observed. A mechanism is proposed to rationalize these results.

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