THE ADDITION OF TRIFLUOROMETHYLHYPOFLUORITE TO HEXAFLUOROPROPENE DIMERS

Author(s): CORVAJA, C; CREMONESE, F; NAVARRINI, W; TONELLI, C; TORTELLI, V.

Source: TETRAHEDRON LETTERS

Volume: 36 Issue: 20 Pages: 3543-3546

DOI: 10.1016/0040-4039(95)00553-O Published: MAY 15 1995

ABSTRACT:

The reaction of trifluomethylhypofluorite with the two anionic dimers of hexafluoropropene leads to the trifluoromethylether adducts in excellent yield. The radical intermediates of the reaction have been detected using the EPR technique.

http://www.sciencedirect.com/science/article/pii/004040399500553O