A new approach to the synthesis of 2,2-difluoro-1,3-dioxolanes

Author(s):NAVARRINI, W;BRAGANTE, L;FONTANA, S;TORTELLI, V; ZEDDA, A.

Source:JOURNAL OF FLUORINE CHEMISTRY

Volume: 71 Issue: 1 Pages: 111-117

DOI: 10.1016/0022-1139(94)03167-X Published: MAR 1995

ABSTRACT:

A direct and versatile way to prepare halogenated 2,2-difluoro-1,3-dioxolanes through the addition of bis-(fluoroxy)difluoromethane (BDM) to halogenated alkenes (CF2=CFCF3, CF2=CFOCF2CF3, CF2=CHCF3, CF3CF=CFCF3, CFCl=CFCl, CFBr=CFBr, CCl2=CCl2, CHCl=CCl2, CHCl=CHCl, CH2=CHCl, CF2=CFCl, (CF3)(2)CFCF=CFCF3, CF2=CFBr, CF2=CF2) has been discovered.

http://www.sciencedirect.com/science/article/pii/002211399403167X